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Question

25.3 g of sodium carbonate, Na2CO3 is dissolved in enough water to make 250 mL of solution. If Sodium carbonate dissociates completely, molar concentration of sodium ion, Na+ and carbonate ions, CO23 are respectively (molar mass of Na2CO3=106 g mol1)

A
0.477 M and 0.477 M
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B
0.955 M and 0.910 M
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C
1.910 M and 0.955 M
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D
1.90 M and 0.910 M
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Solution

The correct option is C 1.910 M and 0.955 M
Molarity=nsolute×1000Vsolution(mL)=25.3×1000106×250=0.955 M
In aquous solution, Na2CO3 dissociates as;
Na2CO32Na++CO23
Molarity of Na+=2×0.955 M
=1.910 M
And, Molarity of CO23=0.955 M

Hence the correct answer is option (c).

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