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Question

A0/2 atoms of X(g) are converted into X+(g) by absorbing energy E1. A0/2 of X+(g) are converted into X(g) with the release of energy, E2. Hence the ionisation energy and the electron affinity of X(g) are repectively _____ and _______.

A
2E1A0,2(E1E2)A0
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B
2E1A0,2(E2E1)A0
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C
(E1E2)A0,2E2A0
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D
None of these
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Solution

The correct option is B 2E1A0,2(E2E1)A0
X(g)X+(g)
Here amount of energy released is ionisation potential.
For Ao2 absorbed energy =Ao2I.E=E1
I.E=2E1Ao
Energy released in the conversion of X to X+ will be ionisation energy
Energy released in the conversion of X to X will be electron affinity.
E2=IE×Ao2+E.AAo2
E.A=2(E2E1)Ao

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