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Question

A metal ion combines with a negative radical containing a chlorine atom. If the number of oxygen atoms in one molecule of the salt is 8, find the valency of the metal and identify the negative radical(s)


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Solution

  • Radicals are an atom or group of atoms with positive or negative charge.
  • The ions formed by the gain of electron(s) are negatively charged and called anions .
  • The ions formed by the loss of electron(s) are positively charged and are called cations.
  • The negative radical with chlorine and oxygen may be hypochlorite (ClO- ),chlorite (ClO2-), chlorate (ClO3-) and perchlorate (ClO4-).
  • All the above radicals are monovalent.
  • It is given that the total oxygen atoms in this compound is 8.
  • Therefore, the negative radical could be ClO2- or ClO4-.
  • Let M be the metal, then ,the formula of the salt can be M(ClO2)4 or M(ClO4)2.
  • The total oxidation state of a compound is zero
  • If the salt is M(ClO2)4, valency of M is 4 and if the salt is M(ClO4)2, valency of M is 2.

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