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Question

An organic compound contains Carbon, Hydrogen and Oxygen. Its elemental analysis gave C,38.71% and H, 9.67%.The empirical formula of the compound would be?


A

CHO

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B

CH2O

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C

CH3O

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D

CH4O

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Solution

The correct option is C

CH3O


The correct option is (C):

Explanation for the correct answer:

CH3O:

Step 1: Mole ratio for Carbon (C), Hydrogen (H) and Oxygen (O)

Element Carbon:

The percentage composition of Carbon : 38.71%

Atomic mass of Carbon: 12

So, Moleratio=%compositionAtomicmass

Moleratio=38.7112=3.22

Element Hydrogen:

The percentage composition of Hydrogen : 9.67%

Atomic mass of Hydrogen: 1

So, Moleratio=%compositionAtomicmass

Moleratio=9.671=9.67

Element Oxygen

The percentage composition of Oxygen: 100-(38.71+9.67)=51.62%

Atomic mass of Oxygen:16

So, Moleratio=%compositionAtomicmass

Moleratio=51.6216=3.22

Step 2: Simple ration for C, H and O.

For carbon (C)

Simpleratio:moleratiosmallestmoleratio=3.223.22=1

Hence, Carbon: 1

For Hydrogen (H)

Simpleratio:moleratiosmallestmoleratio=9.673.22=3

Hence, Hydrogen: 3

For Oxygen (O)

Simpleratio:moleratiosmallestmoleratio=3.223.22=1

Hence, Oxygen: 1

Therefore, the empirical formula of the compound is Option (C): CH3O


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