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Question

Assertion :Extraction of iron metal from iron oxide ore is carried out by heating with coke. Reason: The reaction:


Fe2O3(s)Fe(s)+3/2O2(g)

is a spontaneous process.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion.
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.
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C
Assertion is correct but Reason is incorrect.
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D
Assertion is incorrect but Reason is correct.
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Solution

The correct option is C Assertion is correct but Reason is incorrect.
Iron is obtained from Fe2O3 by heating it with a mixture of coke and CaCO3 in a blast furnace in which CO formed reduces Fe2O3 to Fe.

Fe2O3+3CO2Fe+3CO2

However, the reason is incorrect because the reaction, Fe2O3(s)Fe(s)+32O2(g) is not a spontaneous reaction.

Hence, option C is correct.

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