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Question

Assume 100% ionisation in the following equimolal aqueous solution :

(a) 1m CaCl2 (b) 1m sucrose (c) 1m AlCl3 (d) 1m KCl

Arrange them in the increasing order of osmotic pressure:


A
A<D<B<C
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B

B<D<A<C

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C

C<A<D<B

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D

A<B<D<C

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Solution

The correct option is B

B<D<A<C


Osmotic pressure is directly proportional to the number of ions solution (for equimolal solution)

(A)CaCl2=Ca+2+2Cl- =3 ions

(B) Sucrose (C12 H22 O11) Non electrolyte =1

(C) AlCl3 Al+3 +3Cl- =4ions

(D) KClK+ +Cl- =2

B<D<A<C


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