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Question

At 10 C, the osmotic pressure of urea solution is 500 mm. The solution is diluted and the temperature is raised to 25 C, and the osmotic pressure is found to be 105.3 mm of Hg. Determine the extent of dilution.

A
3 times
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B
10 times
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C
5 times
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D
2 times
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Solution

The correct option is C 5 times
Osmotic pressure of urea solution at 100C
π1=iC1RT1 (i)
Osmotic pressure of urea solution at 250C
π2=iC2RT2 (ii)
From eq 1 and 2 we will have
π1π2=C1×283C2×298
C2=283×105.3500×298×C1 that is
C2=C15

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