$BariumChloride+AluminiumSulphate\to BariumSulphate+AluminiumChloride$

Which of the following balanced chemical equation represent the above chemical reaction correctly?

The correct option is D

+ +

Barium Chloride + Aluminium Sulphate→ Barium Sulphate +Aluminium Chloride.

The skeleton reaction is $BaC{l}_2$ + $A{l}_2(S{O}_4{)}_3$ $\to$ $BaS{O}_4+AlC{l}_3$

1. Consider Aluminium Sulphate compound first because it has more number of atoms, 2 atoms of Al are present on reactant side and 1 atom on product side. To balance Al, take the coefficient of AlCl₃ on product side as 2.

So the equation becomes,$BaC{l}_2$ + $A{l}_2(S{O}_4{)}_3$ $\to$ $BaS{O}_4+2AlC{l}_3$

2. Now consider the set (SO₄) instead of S and O separately because it is present in reactant and product side in the same form. There are 3 sets on reactant side and 1 set on product side, to balance this, take the coefficient of BaSO₄ as 3.

$BaC{l}_2$ + $A{l}_2(S{O}_4{)}_3$ $\to$ $3BaS{O}_4+AlC{l}_3$

3. Now consider Ba, there are 3 atoms on product side and 1 atom on reactant side, to balance it, take the coefficient of $BaC{l}_2$ as 3. The Cl atoms are also balanced.

$3BaC{l}_2$ + $A{l}_2(S{O}_4{)}_3$ $\to$ $3BaS{O}_4+2AlC{l}_3$

The balanced reaction is,

$3BaC{l}_2$ + $A{l}_2(S{O}_4{)}_3$ $\to$ $3BaS{O}_4+2AlC{l}_3$