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Byju's Answer
Standard XII
Chemistry
Bond Order and Enthalpy
BX_3+NH_3→BX_...
Question
B
X
3
+
N
H
3
→
B
X
3
.
N
H
3
+
Heat of adduct formation (
Δ
H
)
The numerical value of
Δ
H
is found to be maximum for:
A
B
F
3
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B
B
C
l
3
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C
B
B
r
3
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D
B
I
3
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Solution
The correct option is
A
B
F
3
B
X
3
.
N
H
3
Adduct
f
o
r
m
n
order
B
I
3
>
B
B
r
3
>
B
C
l
3
>
B
F
3
As in
B
F
3
strong back bonding occur. So adduct
f
o
r
m
n
decreases. Back bonding
α
1
a
d
d
u
c
t
f
o
r
m
n
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Similar questions
Q.
B
X
3
N
H
3
⟶
B
X
3
.
N
H
3
Δ
H
f
= Heat of formation of the adduct. The numerical value of
Δ
H
f
is found to be maximum for:
Q.
The correct order of Lewis acidity of
B
X
3
molecule is
Q.
B
X
3
N
H
3
⟶
B
X
3
.
N
H
3
Δ
H
f
= Heat of formation of the adduct. The numerical value of
Δ
H
f
is found to be maximum for:
Q.
N
2
(
g
)
+
3
H
2
(
g
)
⟶
2
N
H
3
:
Δ
H
=
−
92
k
J
is Haber`s process for manufacture of
N
H
3
.
What is the numerical value of heat of formation of
N
H
3
?
Q.
B
F
3
<
B
C
l
3
<
B
B
r
3
<
B
I
3
Above order is correct for
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