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Question

BX3+NH3BX3.NH3+ Heat of adduct formation (ΔH)
The numerical value of ΔH is found to be maximum for:

A
BF3
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B
BCl3
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C
BBr3
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D
BI3
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Solution

The correct option is A BF3
BX3.NH3
Adduct formn order BI3>BBr3>BCl3>BF3
As in BF3 strong back bonding occur. So adduct formn decreases. Back bonding α1adductformn

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