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Question

Determine CIP priorities for the following compound -

A
CH2CH2CH3> CH(CH3)2 > H > D
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B
CH(CH3)2 > CH2CH2CH3 > - D > - H
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C
CH2CH2CH3> CH(CH3)2 > D > H
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D
D > H > CH2CH2CH3> CH(CH3)2
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Solution

The correct option is B CH(CH3)2 > CH2CH2CH3 > - D > - H
Let’s write it like this

Here, you need to know 2 things:

The isotope with higher atomic mass is given higher priority.
If the first atoms are the same, go to the next set.

Between


C, C, H > C, H, H

So, CH(CH3)2 > CH2CH2CH3 > - D > - H

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