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Question

Fluorine is the most reactive among all the halogens, because of it's:

A
small size
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B
low dissociation energy of F - F bond
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C
large size
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D
high dissociation energy of F - F bond
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Solution

The correct option is D low dissociation energy of F - F bond
Fluorine is the most reactive among all the halogens, because of it's low dissociation energy of FF bond. The dissociation energies (kcal/mol) in F2,Cl2,Br2 and I2 are 38, 57, 45.5 and 35.6 respectively.

In the case of fluorine:
(a) short bond length and larger repulsion between non-bonding electrons lead to low dissociation energy.
(b) absence of multiple bonding leads to low dissociation energy.

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