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Question

Given the limiting molar conductivity as
^0m(HCl)=425.9Ω1cm2mol1
^0m(NaCl)=126.4Ω1cm2mol1
^0m(CH3COONa)=91Ω1cm2mol1
The molar conductivity, at infinite dilution, of acetic (in Ω1cm2mol1) will be:

A
481.5
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B
390.5390.
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C
299.5
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D
516.9
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Solution

The correct option is A 390.5390.
According to Kphlrush's law. Each ion makes a definite contribution to the total molar conductivity of an electrode irrespective of the nature of the other ion
eg for AxBy
Som=Xoλ(Ay+)+Yλ(Bx)
similarly
Λm(CH2COOH)=Λm(CH2COOH)+Λm(HCl)Λm(NaCl)
=91+425.9126.4=390Ω1cm2mol1

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