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Question

If 15 g mass of nitrogen gas is enclosed in a vessel at a temperature 27C. Amount of heat transfered to the gas, so that rms velocity of molecules is doubled is about
[Take R=8.3 J/K mole]

A
14 kJ
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B
6 kJ
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C
0.9 kJ
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D
10 kJ
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Solution

The correct option is D 10 kJ
Given that,
T=27+273=300 K
m=15 g
M=28 g

Heat transferred in closed vessel is given by,
Q=nCvΔT.....(1)

Rms speed is given by
Vrms=3RTM
VrmsT

As Rms speed is doubled, the temperature will be quadrupled
T=4T

For diatomic gas
γdiatomic=75
and
Cv=52R


Putting all the values in the equation 1
Q=nCvΔT=1528×5R2×(4TT)
Q=1528×5×8.32×3×300
Q=10000 J=10 kJ

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