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Question

In a pseudo first order acid catalysed hydrolysis of ester in water the following results were obtained:
t/s 0 30 60 90
[ester]/M 0.55 0.31 0.17 0.085
Which of the following is/are correct for the given reaction?

A
The average rate of reaction between time interval 30 to 60 seconds is 4.67×103molL1s1
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B
Order of reaction is 2.
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C
Pseudo first order rate constant for the acid catalysed hydrolysis of ester is 1.92×102s1
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D
All are correct.
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Solution

The correct options are
A The average rate of reaction between time interval 30 to 60 seconds is 4.67×103molL1s1
C Pseudo first order rate constant for the acid catalysed hydrolysis of ester is 1.92×102s1
rateavg=0.14/30=4.67×103
k=1.92×102

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