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Question

[Ni(CO)4]>[Co(CO)4]>[Fe(CO)4]2 is the correct order with respect to M-C π bond. Where M=Ni, Fe, and Co


A
True
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B
False
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Solution

The correct option is B False
In carbonylate anion, the metal has a greater electron density to
be dispersed, with the result that M-C, π bonding is enhanced in
strength. Hence the correct order is[Ni(CO)4]<[Co(CO)4]<[Fe(CO)4]2. for strength of M - Cπ bond.

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