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Question

Sulphur and the rest of the elements of group 16 are less electronegative than oxygen. Therefore, their atoms cannot accept electrons easily. They can acquire the ns2np6 configuration by sharing two electrons with the atoms of the other elements and thus, exhibit a +2 oxidation state in their compounds. In addition to this, their atoms have vacant d-orbitals in their valence shell. Electrons can be promoted here from s and p-orbitals of the same shell, hence they can show +4 and +6 oxidation states.
Like sulphur, oxygen does not show +4 and +6 oxidation states. The reason is that oxygen:

A
Is a gas, while sulphur is a solid
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B
Has a higher ionization enthalpy when compared to sulphur
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C
Has a higher electron affinity when compared to sulphur
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D
Has no d-orbitals in its valence shell
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Solution

The correct option is D Has no d-orbitals in its valence shell
Sulphur shows +4 and +6 oxidation states due to the presence of vacant 3d orbitals to which electrons can be promoted from 3s and 3p filled orbitals.

Since oxygen atom does not have 2d orbitals, no electron can be promoted.

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