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Question

The intermediate formed during the addition of HCl to propene in the presence of peroxide is:

A
CH3CHCH2Cl
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B
CH3CH2CH2
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C
CH3+CHCH3
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D
CH3CH2+CH2
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Solution

The correct option is B CH3+CHCH3
The intermediate formed during the addition of HCl to propene in the presence of peroxide is CH3CH+CH3. In case of HCl, peroxide has no effect. Secondary carbocation is formed as it is more stable than primary carbocation.

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