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Question

The octahedral complex CoSO4Cl5NH3 exists in two isomeric forms X and Y. Isomers X reacts with AgNO3 to give a white precipitate, but does not react with BaCl2. Isomer Y gives white precipitate with BaCl2 but does not react with AgNO3.
Isomers X and Y are:

A
ionization isomers
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B
linkage isomers
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C
coordinating isomers
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D
solvent isomers
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Solution

The correct option is A ionization isomers
[Co(NH3)5SO4]Cl(X)AgNO3−−−AgClwhite ppt.

[Co(NH3)5Cl]SO4(Y)BaCl2−−BaSO4white ppt.

[X] and [Y] are ionization isomers.

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