The volume of the HCP unit cell is
24√2 r3
Base area of regular hexagon = Area of 6 equilateral triangles each with side ‘a’.
=6√34a2
Height of the unit cell(h) = 2 × Distance between adjacent layers =2×√23 a
∴ Volume of the unit cell = Base Area × height
=(6√34 a2)(2√23 a)=3√2 a3
Putting a = 2r, volume = 24√2 r3