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Question

What is meant by ‘demineralised’ water and how can it be obtained?


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    Solution

    Demineralised water is free from all soluble mineral salts. It does not contain any anions or cations.
    Demineralised water is obtained by passing water successively through a cation exchange (in the H+ form) and an anion exchange (in the OH form) resin.
    During the cation exchange process, H+ exchanges for Na+,Mg2+,Ca2+ and other cations present in water.
    2RH(s)+M2+(aq)MR2(s)+2H+(aq)(1)
    In the anion exchange process, OH exchanges for anions such as CO23,SO24,Cl,HCO3 etc. present in water.
    RNH2(s)+H2O(l)RNH+3.OH(s)
    RNH+3OH(s)+X(aq)RNH+3.X(s)+OH(aq)(2)
    OH ions liberated in reaction (2) neutralize H+ ions liberated in reaction (1), thereby forming water.
    H+(aq)+OH(aq)H2O(l)


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