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Question

When 12.2 g of benzoic acid is dissolved in 100 g of water, the freezing point of solution was found to be 0.93oC(Kf(H2O)=1.86 K kg mol1). Then the number (n) of benzoic acid molecules associated (assuming 100% association) is

A
2.00
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B
2
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C
2.0
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Solution

nPhCOOH(PhCOOH)n

1n=i{As, α=1}

ΔTf=i×kf×m

0.93=1n×1.86×12.2×1000122×100;n=2


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