Which of the following 0.1M complex compound solutions will have the minimum electrical conductivity?
A
Hexammine platinum (IV) chloride
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B
Chloropenta ammine platinum (IV) chloride
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C
Dichloro tetrammine platinum (IV) chloride
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D
Trichloro tetrammine platinum (IV) chloride
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Solution
The correct option is D Trichloro tetrammine platinum (IV) chloride The formula of given complex are as follows: (a) Hexammine platinum (IV) chloirde [Pt(NH3)6]Cl4 (b) Chloropentammine platinum (IV) chloirde [Pt(NH3)5Cl]Cl3 (c) Dichlorotetrammine platinum (IV) chloirde [Pt(NH3)4Cl2]Cl2 (d) Trichlorotriammine platinum (IV) chloirde [Pt(NH3)3Cl3]Cl In aqueous solution the complexes ionise as [Pt(NH3)6]Cl4⇌[Pt(NH3)6]4++4Cl−5ions