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Question

1 mole of a gas AB3 present in 10 L container dissociates into AB2(g) and B2(g).
2AB3(g)2AB2(g)+B2(g)
If the degree of dissociation of AB3 is 80%, then final pressure at 600 K is:
(Given R=0.082 L atm K1mol1)

A
5.88 atm
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B
1.25 atm
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C
10.25 atm
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D
6.88 atm
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Solution

The correct option is D 6.88 atm
2AB3(g)2AB2(g)+B2t=00.100t=eq0.10.080.080.04
Total number of moles per litre (nV)=0.14 mol L1
The final pressure at 600 K is
P =nV×R×T=0.14×0.082×600=6.88 atm

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