2- 2-dichloropropane - A nbsp-B- B isPropenePropanolPropaneEthane

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Synthesis of Aldehydes or Ketones from Hydrocarbons

2, 2-dichloro...

Question

2, 2-dichloropropane $A q . K O H - ---- \to A C l e m m e n s e n - ------- \to r e d u c t i o n B$ , B is

Propanol

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Propene

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Propane

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Ethane

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Solution

The correct option is C Propane
In presence of as KOH, 2, 2-dichloropropane is hydrolyzed to propane-2,2-diol which loses a molecule of water to form acetone (compound A). Clemmensen
reduction of acetone (in presence of Zn/Hg and conc HCl) gives propane (compound B). A carbonyl group is reduced to methylene group.

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2, 2-dichloropropane Aq.KOH−−−−−→AClemmensen−−−−−−−−→reductionB, B is

2, 2-dichloropropane $A q . K O H - ---- \to A C l e m m e n s e n - ------- \to r e d u c t i o n B$ , B is