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Question

22.7 mL of a N10Na2CO3 solution neutralizes 10.2 mL of dilute H2SO4. Find the volume of water to be added to 400 mL of the same H2SO4 solution to make its concentration exactly N10.

A
245 mL
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B
484 mL
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C
480 mL
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D
390 mL
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Solution

The correct option is C 480 mL
We know that for neutralisation:
(NV)Na2CO3=(NV)H2SO4
(0.1×22.7)=(N×10.2)
Normality of H2SO4=0.22 N
Now, this acid is diluted to a new concentration of N10.
Let the amount of water to be added be Vw mL
NintialVintial=NfinalVfinal

(0.22×400)=(0.1×(Vwater+400))
On solving, Vwater=480 mL

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