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Question

A certain oxide of metal M crystallises in such a way that O2− ions occupy hcp arrangement following AB AB... pattern. The metal ions, however, occupy 23rd of the octahedral voids. The formula of the compound is

A
M2O3
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B
M3O
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C
M8/3O3
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D
MO2
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Solution

The correct option is A M2O3
A certain oxide of metal M crystallises in such a way that O2 ions occupy hcp arrangement following AB AB... pattern. The metal ions, however, occupy 23rd of the octahedral voids. The formula of the compound is M2O3
O2 ions occupy hcp arrangement. There are six O2 ions per unit cell. There are 6 octahedral voids per unit cell out of which 23rd or 23×6=4 octahedral voids are occupied with metal ions.
The ratio of number of atoms M:O=4:6=2:3

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