A certain oxide of metal M crystallises in such a way that O2− ions occupy hcp arrangement following ABAB... pattern. The metal ions, however, occupy 23rd of the octahedral voids. The formula of the compound is
A
M2O3
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B
M3O
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C
M8/3O3
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D
MO2
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Solution
The correct option is AM2O3 A certain oxide of metal M crystallises in such a way that O2− ions occupy hcp arrangement following AB AB... pattern. The metal ions, however, occupy 23rd of the octahedral voids. The formula of the compound is M2O3 O2− ions occupy hcp arrangement. There are six O2− ions per unit cell. There are 6 octahedral voids per unit cell out of which 23rd or 23×6=4 octahedral voids are occupied with metal ions. The ratio of number of atoms M:O=4:6=2:3