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Question

A current of dry air was passed through a solution of 2.5 g of a non-volatile solute in 100 g of water and through water alone. The loss in the weight of solution was 1.25 g and that of water was 0.005 g. Calculate the molecular mass of the solute.

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Solution

PoPS loss in weight of pure water
and PS loss in weight of solution
Using PoPSPs=n2n1=m2×M1M2×m1
Given that:
loss of weigt os solution=1.25 g and that of pure water = 0.005g
mass of solute, m2=2.5g
mass of solvent (water), m1=100g
Molar mass of solute M2
molar mass of water, M1=18g/mol
substituting the values in above equation we get:
0.0051.25=2.5×18M2×100
M2=112.5g/mol
molar mass of solute is 112.5 g/mol

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