A metal M readily forms water soluble sulphate MSO4, water insoluble hydroxide M(OH)2 and oxide MO which becomes inert on heating. The hydroxide is soluble in NaOH. The M is
A
Sr
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B
Be
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C
Ca
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D
Mg
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Solution
The correct option is BBe In group 2, the solubility of sulphates decrease down the group. Be and Mg sulphates are highly soluble due to high enthalpy of solvation of smaller Be2+and Mg2+ ions.
BeO and MgO are non reactive on heating, hence they are used in lining furnaces. Be(OH)2 is amphoteric in nature but the hydroxides of Mg, Ca and Sr are basic. Hence Be(OH)2 will dissolve both in acids and alkali. Be(OH)2+H2SO4→Na2Be(OH)4