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Question

A translucent white solid (A) reacts with excess of chlorine to give a yellowish white powder (B). (B) reacts with organic compounds containing OH group converting them into chloro derivatives. (B) on hydrolysis gives (C) and is finally converted to phosphoric acid. (A),(B) and (C) are:

A
P4,PCl3 and H3PO4
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B
P4,PCl5 and H3PO3
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C
P4,PCl3 and POCl3
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D
P4,PCl5 and POCl3
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Solution

The correct option is D P4,PCl5 and POCl3
P4A+10Cl24PCl5B

C2H5OH+PCl5BC2H5Cl+POCl3+HCl

PCl5B+H2OPOCl3C+2HCl

POCl3C+3H2OH3PO4+3HCl
Orthophosphoric acid

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