Among the complex ions, $[C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} C l_{2}]^{+}, [C r C l_{2} (C_{2} O_{4})_{2}]^{3 -}, [F e (H_{2} O)_{4} (O H)_{2}]^{+}, [F e (N H_{3})_{2} (C N)_{4}]^{-}, [C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} (N H_{3}) C l]_{2 +} and [C o (N H_{3})_{4} (H_{2} O) C l]_{2 +},$ the number of complex ion(s) that show(s) cis-trans isomerism is

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Solution

(All the six complexes will show cis-trans isomerism)

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[C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} C l_{2}]^{+}, [C r C l_{2} (C_{2} O_{4})_{2}]^{3 -}, [F e (H_{2} O)_{4} (O H)_{2}]^{+}, [F e (N H_{3})_{2} (C N)_{4}]^{-}, [C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} (N H_{3}) C l]^{2 +}

[C o (N H_{3})_{4} (H_{2} O) C l]^{2 +}

[C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} C l_{2}]^{+}, [C r C l_{2} (C_{2} O_{4})_{2}]^{3 -}, [F e (H_{2} O)_{4} (O H)_{2}]^{+}, [F e (N H_{3})_{2} (C N)_{4}]^{-}, [C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} (N H_{3}) C l]^{2 +}

[C o (N H_{3})_{4} (H_{2} O) C l]^{2 +}

{[C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} C l_{2}]}_{2}^{+}, {[C r C l_{2} (C_{2} O_{4})_{2}]}_{2}^{3 -}, {[F e (H_{2} O)_{4} (O H)_{2}]}_{2}^{+}, {[F e (N H_{3})_{2} (C N)_{4}]}_{3}^{-}, {[C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} (N H_{3}) C l]}_{2}^{2 +} a n d {[C o (N H_{3})_{4} (H_{2} O) C l]}_{3}^{2 +}

(i) [C o (N H_{3})_{4} (H_{2} O) C l]^{2 +} (i i) [P t (N H_{3})_{2} C l_{2}] (i i i) [C o C l_{2} (e n)_{2}]^{+} (i v) [C r (H_{2} O)_{5} C l] C l_{2} (v) [F e (N H_{3})_{2} (C N)_{4}]^{-} (v i) [C r C l_{2} (o x)_{2}]^{3 -} (v i i) K [C o (H_{2} O)_{2} (o x)_{2}] (v i i i) [C o (N H_{3})_{2} C l_{2} (e n)]^{+} (i x) [C o (e n)_{3}] C l_{3}

cis-trans

Q: FIND WHETHER TRANS OR CIS ISOMER.

CH₂ = C (COOH)₂

ANS : CIS (in book)

but I think this compound doesn't shows isomerism

if it does , explain.

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