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Question

Amploteric hydroxides react with both alkalies and acids. Which of the following Group 2 metal hydroxides is soluble in sodium hydroxide?
(a) Be(OH)2 (b) Mg(OH)2 (c) Ca(OH)2 (d) Ba(OH)2

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Solution

Answer: (a) Be(OH)2

The solubility of hydroxides of alkaline earth metals increases from Be to Ba, in water Be(OH)2 and Mg(OH)2 are almost insoluble.
Due to high hydration enthalpy and high lattice energy

Be(OH)2 is not soluble in water Be(OH)2 is an amploteric hydroxide. With acids, Be(OH)2 is neutralised giving salts.


Be(OH)2+2HClBeCl2+2H2O
Be(OH)2 reacts with NaOH also forming beryliate.
Be(OH)2+2NaOHNa2BeO2+2H2O


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