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Question

An alkaline earth metal ‘M’ readily forms water-soluble sulphate and water-insoluble hydroxide. Its oxide MO is very stable to heat and does not have a rock-salt structure. M is


A

Ca

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B

Be

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C

Mg

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D

Sr

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Solution

The correct option is B

Be


Explanation for correct option:

(B) Be

  1. As Be is smaller is size so it forms water-soluble sulphate and water insoluble hydroxides.
  2. Oxides of Be are very stable to heat due to increase in degree of polymerisation.
  3. Be do not have rock salt structure because it form sodium beryllate on dissolving in sodium hydroxide.

Explanation for incorrect option:

(A) Ca

  1. Sulphates of calcium are insoluble in water due to high hydration enthalpy.
  2. Hydroxides of calcium are also slightly soluble in water.
  3. Hence Ca is not metal M .

(C) Mg

  1. Mg does not react with sodium hydroxide to form salt.
  2. Hence Mg is not metal M .

(D) Sr

  1. As Sr is larger in size so it forms water insoluble sulphates and slightly soluble hydroxides.
  2. Hence Sr is not metal M .

Hence option B is correct, Be is metal M.


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