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Question

An element has a face centred cubic structure with a cell edge of 0.2nm. calculate its density in gm/cm3 if 400gm of this element contains 4.8*10^24 atoms

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Solution

Each unit cell has:

8 corner atoms, each shared by 8 unit cells = (1/8)(8) = 1 atom
6 face atoms, each shared by 2 faces = (1/2)(6) = 3 atoms
Total: 4 atoms per unit cell

1nm=10-9 m

V = a3 = (0.2 x 10-9 m)3 = 8 x 10-30 m3 = 8 x 10-24 cm3

Now do a proportion to get the mass of the 4 atoms in a unit cell:

400 g → 4.8 x 1024 atoms

400/4.8 x 1024g → 1 atoms

x g→ 4 atoms



x = 4 · 400 / (4.8 x 1024) g ≅ 3.33 x 10-22 g

ρ = m/V = (3.33 x 10-22 g) / (8 x 10-24 cm3) ≅ 41.625 g/cm3

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