The correct option is
B Assertion and reason both are true, reason is correct explanation of assertion.
Analysing the assertion
When a solution of chelating ligands is added to a solution containing toxic metals, the ligands chelate the metal ions by the formation of a stable cyclic complex.
Thus, toxic metal ions are removed by chelating ligands.
Example: EDTA (hexadentate ligand) forms a stable metal chelate and is used to remove toxic metal ions.
So, the assertion is a correct statement.
Analysing the reason
Chelating ligands form stable cyclic complexes with metal ions. Thus, the chelate complexes tend to be more stable. So, the reason is also a correct statement.
Hence, both the assertion and the reason are correct statements, and the reason is the correct explanation for the assertion.
So, option (A) is the correct answer.