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Question

Calculate the wave number for the shortest wavelength transition in Brackett series for atomic hydrogen.

A
6.5×106 m1
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B
6.75×104 m1
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C
6.85×105 m1
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D
6.9×107 m1
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Solution

The correct option is C 6.85×105 m1
For Brackett series, all transitions take place from higher levels to n=4 level.
Wavenumber, v=1λ=RH[1421n2]

For minimum or the shortest wavelength, n=
Hence, v=1λmin=RH[14212]

=1.09677×107 m116

v=6.85×105 m1

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