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Question

Compare the alkali metals and alkaline earth metals with respect to

A lonization enthalpy

B Basicity of oxides

C Solubility of hydroxides

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Solution

Comparison between alkali metals and alkaline earth metals

Property

lonization enthalpy

Alkali Metals

Alkali metals have lowest ionization enthalpies in respective periods.
This is because of their large atomic sizes. Also, they lose their only valence electron easily as they attain stable noble gas configuration after losing it.

Alkaline earth metal

Alkaline earth metals have smaller atomic size and higher effective nuclear charge as compared to alkali metals.
This causes their first ionization enthalpies to be higher than that of alkali metals. However, their second ionization enthalpies are less than the corresponding alkali metals. This is because alkali metals, after losing one electron, acquires noble gas configuration, which is very stable

Basicity of oxides

Alkali Metals

The oxides of alkali metals are very basic in nature..
This happens due to the hightly electropositive nature of alkali metals, which makes these oxides highly ionic. Hence, they readily dissociate in water to give hydroxide ions.

Alkaline earth metal

The oxides of alkaline earth metals are quite basic but less basic compared to those of alkali metals.
This is because alkaline earth metals are less electropositive than alkali metals

Solubility of hydroxides

Alkali Metals

The hydroxides of alkali metals are more soluble than those of alkaline earth metals.

Alkaline earth metal

The hydroxides of alkaline earth metals are less soluble than those of alkali metals.
This is due to the high lattice energies of alkaline earth metals. Their higher charge densities (as compared to alkali metals) account for higher lattice energies.

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