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Question

Discuss the role of Lewis acids in the preparation of aryl bromides and chlorides in the dark.

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Solution

Lewis’s acids are electron-deficient species. They are responsible for inducing heterolytic fission in halogen molecules. The role of Lewis acid is to produce an electrophile, The electrophile produce will attack electron-rich benzene ring to produce aryl bromides and chlorides

Preparation of aryl bromide

AlBr3+Br2[AlBr4]+Br+

AlBr3+Br2[AlBr4]Br+



Preparation of aryl chloride

AlCl3+Cl2[AlCl4]+Cl+

This electrophile will attack benzene ring


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