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Byju's Answer
Standard XII
Chemistry
Colours in Coordination Compounds
FeCl_3 solut...
Question
F
e
C
l
3
solution gives blood red colour with
N
H
4
S
C
N
. If
H
2
S
gas is passed and filtered, then filtrate does not give red colour with
N
H
4
S
C
N
.
If true enter 1, else enter 0.
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Solution
F
e
C
l
3
solution gives blood red colour with
N
H
4
S
C
N
.
F
e
C
l
3
+
N
H
4
S
C
N
→
[
F
e
(
S
C
N
)
]
C
l
2
r
e
d
+
N
H
4
C
l
F
e
C
l
3
changes to
F
e
C
l
2
on passing
H
2
S
.
Hence, no colour change with
N
H
4
S
C
N
is observed after passing
H
2
S
.
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0
Similar questions
Q.
F
e
C
l
3
gives blood red colour with
N
H
4
S
C
N
. If
H
2
S
gas is passed and filtered then filtrate does not give red colour with
N
H
4
S
C
N
.
It is due to the presence on:
Q.
If true enter 1, else enter 0.
F
e
C
l
3
gives blood red colour of formula
[
F
e
(
C
N
S
)
(
H
2
O
)
y
]
2
+
with KCNS. Here y = 5.
Q.
(A) (yellow coloured solution) changes to light green coloured solution (B) on passing
H
2
S
gas. (A) and (B) both give white precipitate with
B
a
C
l
2
solution, insoluble in conc.
H
C
l
. A gives blue coloured ppt (C) with
K
4
[
F
e
(
C
N
)
6
]
, (B) does not. Here,
(A) :
F
e
C
l
3
(B) :
F
e
C
l
2
(C) :
F
e
4
[
F
e
(
C
N
6
)
]
3
If true enter 1, else enter 0.
Q.
N
H
4
S
C
N
gives red colour with
F
e
3
+
Due to the formation of
[
F
e
(
S
C
N
)
]
2
+
.
If the given statement is true enter 1 else 0.
Q.
C
r
2
(
S
O
4
)
3
solution produce green colour with
N
a
2
O
(
e
x
c
e
s
s
)
and yellow colour with
N
a
2
O
2
(
e
x
c
e
s
s
)
.
If true enter 1 else 0.
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