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Question

Given below are the two statements : one is labelled as Assertion (a) and the other is labelled as Reason (R).

Assertion (A) : Aluminium is extracted from bauxite by the electrolysis of molten mixture of \(Al_{2}O_{3}\) with cryolite.

Reason(R) : The oxidation state of \(Al\) in cryolite is \(+3\).

In the light of the above statements , choose the most appropriate answer from the options given below :

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Solution

(A) is correct - Aluminium is extracted from bauxite by electrolysis of molten mixture of \(Al_{2}O_{3}\) with cryolite
\(Na_3AlF_6: \\3+x-6=0\\x=+3\)
Statement given in (R) is correct i.e, oxidation state of \(Al\) in cryolite (\(Na_{3}AlF_{6})\) is +3 but it is not correct reason of (A)

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