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Question

How do you convert chlorobenzene to phenol?


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Solution

Conversion of Chlorobenzene to Phenol:

Dow's method:-

  • Dow’s method is a process of converting Chlorobenzene into Phenol.
  • Chlorobenzene is treated with aqueous Sodium hydroxide at temperatures of 623K and 300atm to obtain the Phenoxide ion.
  • This Sodium phenoxide ion is then combined with Dilute Hydrochloric acid to produce the final product as a Phenol.

Step 1: Formation of Phenoxide ion

  • The Chlorobenzeen is being reacted with aqueous 6-8% Sodium hydroxide(NaOH) at 623K,300atm to form Phenoxide ion.

Step 2: Formation of Phenol

  • The Phenoxide ion thus formed is reacted with dilute Hydrochloric acid(HCl) to form Phenol.

This conversion of Chlorobenzene to Phenol is a 2 step reaction

Therefore, Chlorobenzene is converted to Phenol using Dow's method.


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