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Question

If H2S is passed into the above mixture in the presence of HCl, which ion will be precipitated first?

A
SnS
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B
CdS
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C
NiS
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D
SnS and CdS (both together)
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Solution

The correct option is C SnS
Compound with higher solubility constant will be more soluble.
Here, among given compounds SnS(Ksp=8×1029) has the least solubility constant. So its solubility will be minimum and it will precipitate first.

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