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Question

In a cell that utilizes the reaction Zn(s) +2H+ (aq) Zn2+(aq)+H2(g) addition of H2SO4 to cathode compartment, will:

A
lower the E and shift equilibrium to the left
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B
lower the E and shift the equilibrium to the right
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C
increase the E and shift the equilibrium to the right
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D
increase the E and shift the equilibrium to the left
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Solution

The correct option is C increase the E and shift the equilibrium to the right
Zn(s) +2H+ (aq) Zn2+(aq)+H2(g)

E=E00.0592log[Zn+2][H+]2

So as we add sulphuric acid, conc. of hydrogen ion increases and equilibrium shifts to right.
Also according to the equation emf of the cell will be increased by adding acid.

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