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Question

In a unit cell atoms A B C and D are present at corners face centres bodycentre and edge centres respectively.if atoms touching one of the plane passing through two diagonally opposite edges are removed then formula of compound is

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Solution

by removing the plane passing through diagonally opposite edges
4 corners ,2face centres,1body centre and 2edge centres will be removed. therefore the effective atoms at corners wold be 4/8,at face centre4/2 and at edge centre 10/4.
A:B:C:D= 1:4:0:5
thus formula is AB4D5

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