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Question

In a unit cell, atoms A,B,C and D are present at corners, face-centres, body-centre and edge-centres respectively. If atoms touching one of the plane passing through two diagonally opposite edges are removed, then formula of compound is:

A
ABCD2
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B
ABD2
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C
AB2D2
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D
AB4D5
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Solution

The correct option is D AB4D5
Initially, atoms effectively in the lattice are as follows:
A8×18,B6×12,C1,D12×14
After the removal of atoms,
atoms left at the corners=84=4A4×18=12
atoms left at the face center=62=4B4×12=2
atoms left at the body center=0C0
atoms left at edge center=122=10D10×14=2.5
ratio of A:B,C:D=0.5:2:0:2.5=1:4:0:5
Hence, compound formula is AB4D5

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