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Question

In nitration of benzene using conc. H2SO4 and conc. HNO3, the role of nitric acid is as

A
an acid
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B
a base
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C
a reducing agent
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D
an oxidising agent
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Solution

The correct option is B a base
Nitration is electrophilic substitution reaction. In its first step HNO3 takes protons from sulphuric acid and then forms NO+2 as an attacking electrophile for the reaction. So, here HNO3 acts as a base.

Mechanism of reaction is shown as:

So, (b) is correct.

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