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Question

In the crystal field of the complex [Fe(Cl)(CN)4(O2)]4−, the electronic configuration of the metal is found to be t62ge0g. Which of the following is true about this complex ion?

A
It is a paramagnetic complex
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B
OO bond length will be less than what is found in the O2 molecule
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C
Its IUPAC name will be chlorotetracyanosuperoxidoferrate(II) ion
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D
It is a diamagnetic complex
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Solution

The correct options are
C Its IUPAC name will be chlorotetracyanosuperoxidoferrate(II) ion
D It is a diamagnetic complex
The electronic configuration of Fe is given as t62ge0g. This lets us conclude that Fe is in +2 oxidation state. Balancing the charges, we see that the O2 given is nothing but superoxide ligand. We know that the OO bond length in superoxide is longer than that in oxygen. [Fe(Cl)(CN)4(O2)]4 will be called chlorotetracyanosuperoxidoferrate(II) ion.
We also know that Cynaide is a strong field ligand and hence it will cause pairing in the t2g orbitals. This lets us conclude that the said complex will be diamagnetic in nature.

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