In the crystal field of the complex [Fe(Cl)(CN)4(O2)]4−, the electronic configuration of the metal is found to be t62ge0g. Which of the following is true about this complex ion?
A
It is a paramagnetic complex
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B
O−O bond length will be less than what is found in the O2 molecule
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C
Its IUPAC name will be chlorotetracyanosuperoxidoferrate(II) ion
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D
It is a diamagnetic complex
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Solution
The correct options are C Its IUPAC name will be chlorotetracyanosuperoxidoferrate(II) ion D It is a diamagnetic complex The electronic configuration of Fe is given as t62ge0g. This lets us conclude that Fe is in +2 oxidation state. Balancing the charges, we see that the O2 given is nothing but superoxide ligand. We know that the O−O bond length in superoxide is longer than that in oxygen. [Fe(Cl)(CN)4(O2)]4− will be called chlorotetracyanosuperoxidoferrate(II) ion. We also know that Cynaide is a strong field ligand and hence it will cause pairing in the t2g orbitals. This lets us conclude that the said complex will be diamagnetic in nature.