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Standard XII
Chemistry
Reactivity with Halogens and Hydrogen (Group 2)
Limiting mola...
Question
Limiting molar conductivity of which among thefollowing ion is maximum in water at 298 K(1) H\ast(2) Nat40(3) K\ast(4) Ca2+
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Q.
Limiting molar conductivity for some ions is given(in S
c
m
2
m
o
l
−
1
):
N
a
+
=
50.1
,
C
l
−
=
76.3
,
H
+
=
349.6
,
C
H
3
C
O
O
−
=
40.9
,
C
a
2
+
−
119.0
.
What will be the limiting molar conductivities
(
Λ
o
m
)
of
C
a
C
l
2
,
C
H
3
C
O
O
N
a
and
N
a
C
l
respectively?
Q.
At
298
K
, the limiting molar conductivity of a weak monobasic acid is
4
×
10
2
S
c
m
2
m
o
l
−
1
. At
298
K
, for an aqueous solution of the acid the degree of dissociation is
α
and the molar conductivity is
y
×
10
2
S
c
m
2
m
o
l
−
1
. At
298
K
, upon
20
times dilution with water, the molar conductivity of the solution becomes
3
y
×
10
2
S
c
m
2
m
o
l
−
1
The value of
y
is
Q.
Limiting molar conductivities of
M
g
2
+
and
C
l
−
ions are 106.0 S.cm
2
. mol
−
1
and
76.3 S.cm.
2
. mol
−
1
respectively. Calculate the limiting molar conductivity of
M
g
C
l
2
.
Q.
The values of limiting ionic conductance of
H
+
and
H
C
O
O
−
ions are respectively
347
and
58
S
c
m
2
m
o
l
−
1
.
If the molar conductance of 0.025 M methanoic acid at 298 K is
40
S
c
m
2
m
o
l
−
1
, the dissociation constant of methanoic acid at 298 K is:
Q.
If molar conductivity of
C
a
2
+
and
C
l
−
ions are
119
and
71
S
c
m
2
m
o
l
−
1
respectively, then the molar conductivity of
C
a
C
l
2
at infinite dilution is
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