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Question

Match the extraction processes listed in Column I with metals listed in Column II.


Column IColumn IIA.Selfreductionp.LeadB.Carbon reductionq.SilverC.Complex formation and displacement by metalr.CopperD.Decomposition of iodides.Boron

A
A. p, r; B. q,s; C. q; D. s.
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B
A. p, r; B. p; C. q; D. s.
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C
A. p, r; B. s; C. q; D. s.
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D
A. r; B. p,s; C. q; D. s.
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Solution

The correct option is B A. p, r; B. p; C. q; D. s.
Self-reduction is exhibited by both lead and copper.
PbS+2PbO3Pb+SO2
Cu2S+2Cu2O6Cu+SO2

Surprisingly, lead also undergoes carbon reduction!
The MacArthur-Forrest process is used for the hydrometallurgical extraction or refining of Silver and Gold.

As for boron, it's iodide is unstable above a particular temperature. So crude metal is converted into its iodide (in a sealed container) and then
the iodide is decomposed by heating to get pure metal.

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