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Question

Methane cannot be prepared by :

A
Wurtz reaction
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B
Soda Lime process
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C
Kolbe's reaction
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D
Sabatier-senderens reaction
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Solution

The correct options are
A Wurtz reaction
C Kolbe's reaction
D Sabatier-senderens reaction
Wurtz reaction: It is a coupling reaction thus, two alkyl halide will combine to form higher alkane. Hence, the smallest alkane that can be formed is ethane.
RX+2Na+XRRR+2NaX

Kolbe's electrolysis: Here, the salt of carboxylic acid will undergo decarboxylation to give alkanes.
CH4 can't be prepared by this method. The smallest alkane that can be formed is ethane (C2H6)
2RCOOK+2H2OelectrolysisRR+2CO2+2KOH+H2

Sabatier senderens reaction: Here, unsaturated hydrocarbon is reduced to alkane. The minimum carbon chain of unsaturated hydrocarbon is two i.e., Ethene. Hence, it reduced to form Ethane.
CnH2n+H2NiCnH2n+2

Soda Lime reaction: Here, carboxylic acid will undergo decarboxylation to form alkane containing one C atom less than the carboxylic acid.
Thus, acetic acid will form methane by Soda Lime reaction.
CH3COOHNaOHCH3COONa+H2O
CH3COONa+NaOHCaOΔCH4+Na2CO3.

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