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Question

A solution containing 62 g ethylene glycol in 250 g water is cooled to 10C. If Kf for water is 1.86 K kg mol1, the amount of water (in g) separated as ice is

A
48
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B
32
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C
16
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D
64
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Solution

The correct option is D 64
Freezing point depression of a solution is given by,
Tf=Kf×m
where,
Tf is the depression in freezing point.
Kf is molal depression constant.
m is molality of solution.
Molality (m)=wsoluteM×1000Wsolvent
where,
w is weight of solute
W is weight of solvent
M is molar mass of the solute

10=1.86×62×100062×Wsolvent

Wsolvent=1.86×100010

=186 g

Give amount of H2O is 250 g

The amount of water separated as ice,
=250186=64 g

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